For example, (C 6 H 5)(CH 3) 2 C + is referred to as a "benzylic" carbocation. This colourless liquid is a lachrymator and is used as a building block in organic synthesis. Physical property data is provided to ChemIDplus by SRC, Inc. 29, Pg. ; Gutch, P.K., Gas chromatographic retention indices of tear gases on capillary columns, J. Benzal chloride and benzotrichloride give mixtures of alkylation and reduction products on reaction with Et 3 Al etherate. Benzyl chloride for synthesis. Nomenclature. 65, 1982. BRAIN AND COVERINGS: RECORDINGS FROM SPECIFIC AREAS OF CNS. 30(3), Pg. Labor Hygiene and Occupational Diseases. Vol. Corrosive/Harmful/Lachrymatory/Moisture Sensitive/Store under Argon, DANGER: CORROSIVE, burns skin, eyes, and lungs, P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a. Treatment of benzal chloride with sodium gives stilbene. 100-44-7, EC Number 202-853-6. Trivinylaluminum does not react with benzyl chloride. The reaction proceeds by the free radical process, involving the intermediacy of free chlorine atoms. CAS No. Incompatible with strong oxidizing agents, water, alcohols, strong bases.Reacts violently with DMSO and vigorously with alkalies. This conversion involves hydrolysis in the presence of base:[2], InChI=1S/C7H6Cl2/c8-7(9)6-4-2-1-3-5-6/h1-5,7H, Except where otherwise noted, data are given for materials in their, Ullmann's Encyclopedia of Industrial Chemistry, https://en.wikipedia.org/w/index.php?title=Benzal_chloride&oldid=934827613, Creative Commons Attribution-ShareAlike License, 205 °C (401 °F; 478 K) (82 °C at 10 mmHg), This page was last edited on 8 January 2020, at 18:53. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agency’s EPISuite, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the. 98-87-3 - CAHQGWAXKLQREW-UHFFFAOYSA-N - Benzal chloride - Similar structures search, synonyms, formulas, resource links, and other chemical information. Da Wikipedia, l'enciclopedia libera. Vol. Combustible. Stable. 40(1), Pg.
98-87-3 Modello 3D ( JSmol) Interactive immagine; Beilstein di riferimento. CopyCopied, InChI=1S/C7H5ClO/c8-7(9)6-4-2-1-3-5-6/h1-5H
Naturwiss. Preparation. CopyCopied, PASDCCFISLVPSO-UHFFFAOYSA-N
Benzal cloruro - Benzal chloride. 6, 1986. Vol. [1] This colourless liquid is a lachrymator and is used as a building block in organic synthesis. Z. Wilhelm-Pieck-Univ. 1972, LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION. Benzal chloride is an organic compound with the formula C 6 H 5 CHCl 2. cloruro Benzal nomi nome IUPAC preferito (Diclorometile) benzene. Overall Carcinogenic Evaluation: Group 2A, Threshold Planning Quantity (TPQ) = 500 lb, 4-05-00-00817 (Beilstein Handbook Reference). Most benzal chloride main industrial use is as a precursor to benzaldehyde. Aerospace Medical Research Laboratory Report. Derivatization of Amines, Amino Acids, Amides and Imides for GC Analysis, Marcel Dekker, Inc, New York - Basel, 2001, 224. ass: Standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Heat rate: 3 K/min; Start T: 40 C; End T: 325 C; CAS no: 98884; Active phase: DB-1; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Sun, G.; Stremple, P., Retention index characterization of flavor, fragrance, and many other compounds on DB-1 and DB-XLB, 2003. ass: Standard non-polar; Column diameter: 0.32 mm; Column length: 30 m; Column type: Capillary; Heat rate: 8 K/min; Start T: 60 C; End T: 200 C; Start time: 2 min; CAS no: 98884; Active phase: DB-1; Carrier gas: N2; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Gandhe, B.R. Rostock Math. Reihe, 33, 1984, 6-9. ass: Standard non-polar; Column type: Capillary; CAS no: 98884; Active phase: Polydimethyl siloxanes; Data type: Normal alkane RI; Authors: Zenkevich, I.G., Encyclopedia of Chromatography. 92, 1975. umn class: Standard non-polar; Column length: 3 m; Column type: Packed; Start T: 150 C; CAS no: 98884; Active phase: SE-30; Carrier gas: Ar; Substrate: Gas Chrom Q (80-100 mesh); Data type: Kovats RI; Authors: Tiess, D., Gaschromatographische Retentionsindices von 125 leicht- bis mittelfluchtigen organischen Substanzen toxikologisch-analytischer Relevanz auf SE-30, Wiss. 184. In IUPAC nomenclature the prefix benzyl refers to a C 6 H 5 CH 2 substituent, for example benzyl chloride or benzyl benzoate.Benzyl is not to be confused with phenyl with the formula C 6 H 5.The term benzylic is used to describe the position of the first carbon bonded to a benzene or other aromatic ring. Benzal chloride is produced by the free radical chlorination of toluene, being preceded in the process by benzyl chloride (C6H5CH2Cl) and followed by benzotrichloride (C6H5CCl3): Benzylic halides are typically strong alkylating agents, and for this reason benzal chloride is treated as a hazardous compound. NIST Mass Spectrometry Data Center., 2007. Structure, properties, spectra, suppliers and links for: Benzoyl chloride, 98-88-4. Altri nomi benzilico dicloruro; cloruro benzilidene; α, α-Dichlorotoluene; PHCL 2 H; Identifiers Numero CAS. CopyCopied, CSID:7134, http://www.chemspider.com/Chemical-Structure.7134.html (accessed 13:26, Nov 12, 2020)
IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. In this way, approximately 100,000 tonnes are produced annually. c1ccc(cc1)C(=O)Cl
Gigiena i Sanitariya. - Find MSDS or SDS, a COA, data sheets and more information. Chromatogr., 479, 1989, 165-169. class: Semi-standard non-polar; Column diameter: 0.25 mm; Column length: 30 m; Column type: Capillary; Description: Multi-step temperature program; T(initial)=60C; T(final)=270C; CAS no: 98884; Active phase: VF-5MS; Carrier gas: He; Phase thickness: 0.25 um; Data type: Linear RI; Authors: Tret'yakov, K.V., Retention Data. Vol. Benzyl chloride is prepared industrially by the gas-phase photochemical reaction of toluene with chlorine:. Benzal chloride is an organic compound with the formula C6H5CHCl2. ; Malhotra, R.C. Gigiena Truda i Professional'nye Zabolevaniya. For English translation, see HYSAAV. The reaction of optically active 1-phenylchloroethane with Et 3 Al in chloroethane solvent has been studied at −65 °C. Safety glasses, good ventilation, gloves. ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agency’s EPISuite, Compounds with the same molecular formula, Search Google for structures with same skeleton, colourless or faintly yellow liquid with a penetrating odour. C 6 H 5 CH 3 + Cl 2 → C 6 H 5 CH 2 Cl + HCl. TR-72-62, Pg.
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